I assume that you are looking for Poly(methyl methacrylate) or PMMA, which was developed in Germany in the late 1920's. This product was marketed by the German firm Rohm & Haas as Plexiglas (only one s) in 1933, although it generically existed prior to that time, and today is widely known by a number of names such as Lucite, Perspex, etc. It was transparent, shatter resistant and lighter than glass, but was not widely used in automotive windshields due to its poor resistance to scratching.